Co-Ligand Engineering of d10 Metal-Based Homochiral Coordination Polymers: Synthesis, Optical Properties, and Photoinduced Transformations
- 주제(키워드) Homochiral Coordination Polymers , Optical Properties , Second-Harmonic Generation , Photoinduced Transformations
- 발행기관 서강대학교 일반대학원
- 지도교수 옥강민
- 발행년도 2026
- 학위수여년월 2026. 8
- 학위명 박사
- 학과 및 전공 일반대학원 화학과
- 세부분야 해당없음
- 실제URI http://www.dcollection.net/handler/sogang/000000083380
- UCI I804:11029-000000083380
- 본문언어 영어
- 저작권 논문은 저작권에 의해 보호받습니다.
목차
1. Introduction 24
1.1. Noncentrosymmetric （NCS） Materials 24
1.2. Homochiral Coordination Polymers （HCPs） 25
1.3. Constructing Rigid Frameworks of HCPs as Optical Materials 28
1.4. Solid-State Structural Transformations in HCPs 30
1.5. Co-ligand Engineering Strategy for Multifunctional HCPs 31
1.6. References 34
2. Multifunctional d10 Metal-Based Homochiral Coordination Polymers Exhibiting Photoluminescence and Second-Harmonic Generation 46
2.1. Tunable Photoluminescence and Efficient Second-Harmonic Generation with Circular Dichromic Response in [M2（RIAP）2（bpy）2] and [M2（SIAP）2（bpy）2] （M = Zn and Cd） 46
2.1.1. Experimental Section 46
2.1.2. Results and Discussion 72
2.1.3. Summary 98
2.1.4. References 99
3. Zn-Based Homochiral Coordination Polymers Undergoing Ordered and Disordered Structural Transformations by Photoinduced [2+2] Cycloaddition 103
3.1. Dimensional Transformation in [Zn2（SIAP）2（dpe）4（H2O）4]·6H2O and [Zn2（RIAP）2（dpe）4（H2O）4]·6H2O undergoing [2+2] Photocycloaddition 103
3.1.1. Experimental Section 103
3.1.2. Results and Discussion 127
3.1.3. Summary 149
3.1.4. References 150
3.2. Stimuli-Responsive Structural Transformation in [Zn2（SIAP）（dpe）2（OH）（H2O）]·NO3·2H2O and [Zn2（RIAP）（dpe）2（OH）（H2O）]·NO3·2H2O 152
3.2.1. Experimental Section 152
3.2.2. Results and Discussion 174
3.2.3. Summary 204
3.2.4. References 205
4. Conclusion 208
5. Publications and Corresponding Chapter 213
