Formation of Wrinkling Patterns for Flexible Electrodes by Direct Printing
직접 프린팅을 통한 주름패턴 제작 및 유연전극으로써의 활용
- 주제어 (키워드) wrinkled electrode , direct printing , flexible electronics , wearable electrochemical sensor
- 발행기관 서강대학교 일반대학원
- 지도교수 신관우
- 발행년도 2023
- 학위수여년월 2023. 8
- 학위명 석사
- 학과 및 전공 일반대학원 화학과
- 실제 URI http://www.dcollection.net/handler/sogang/000000076326
- UCI I804:11029-000000076326
- 본문언어 영어
- 저작권 서강대학교 논문은 저작권 보호를 받습니다.
초록 (요약문)
Forming a flexible electrode is useful in the field of wearable electronics. One of the most effective ways to form flexible electrode is wrinkling patterns on the elastomeric substrate to minimize the effect of mechanical strain. However, most of wrinkled electrodes need pre-stretching or thermal expansion which are complex to fabricate. These methods also make wrinkles on the whole substrate, not the desired part. Here, we report new method to fabricate wrinkled electrode on the local part, direct printing. It made wrinkles on the elastomer surface by solventinduced spontaneous swelling. We discovered that triethyleneglycol monoethyl ether (TGME) plays an important role to last wrinkles permanently on the PDMS surface. Direct printing used TGME-based ink and PDMS as substrate to make wrinkled electrode. Wrinkled electrodes showed higher resistance to the tensile bending compared to the non-wrinkled electrodes. The durability came from enlarged surface of aligned wrinkles. In addition, we applied this wrinkle system to the electrochemical sensor (ECS). ECS detects physiological parameters to monitor body condition. It is useful when it can detect glucose or lactate attached right on the body to monitor without sample collection. We designed and printed wrinkle-based ECS and showed its printability and repeatability via cyclic voltammetry (CV). It maintained stable CV curve under mechanical bending which means it has possibility for flexible wearable sensor. With this simplified method, direct printing, we opened a new way to fabricate flexible electrode easily. The wrinkled electrodes are expected to be used as variety of application such as wearable sensor or flexible electronics.
more