Acid treatment of FeRu NPs@MSNs Catalyst for Hydrogenation Reaction of Quinoline
- 주제어 (키워드) Hydrogenation , Quinoline , FeRu Nanoparticle
- 발행기관 서강대학교 일반대학원
- 지도교수 서원석
- 발행년도 2023
- 학위수여년월 2023. 2
- 학위명 석사
- 학과 및 전공 일반대학원 화학과
- 실제 URI http://www.dcollection.net/handler/sogang/000000070134
- UCI I804:11029-000000070134
- 본문언어 영어
- 저작권 서강대학교 논문은 저작권 보호를 받습니다.
초록 (요약문)
It remains a difficult task to create a heterogeneous catalyst that is highly active, selective, affordable, non-hazardous, and more stable for the hydrogenation process of quinoline. Herein, we prepared hcp-FeRu nanoparticles inside mesoporous silica nanospheres (MSNs) through thermal hydrogen reduction of metal precursor (FeRu@MSNs). We controlled the shell thickness of hcp-FeRu by using different HCl concentrations, thereby etching the surface of transition metal (Fe) atoms. The resulting nanocrystals were characterized by XRD, TEM, and EDX. The FeRu@Ru NPs exhibited a substantially enhanced activity in the hydrogenation of quinoline to 1,2,3,4-tetrahydroquinoline (1THQ) or decahydroquinoline under mild conditions in the water. We illustrated catalytic activities of noble metal (Ru) could be improved by introducing first-row transition metals (Fe) by promoting the electronic interaction between noble metals and transition metals.
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