서강대학교

초록/요약 도움말

In this work, we report surface-modified nickel (Ni) wire/NiCo2O4/reduced graphene oxide (Ni/NCO/RGO) electrodes fabricated by a combination of facile solvothermal and hydrothermal deposition methods for wire-shaped supercapacitor application. The effect of Ni wire etching on the microstructural, surface morphological and electrochemical properties of Ni/NCO/RGO electrodes was investigated in detail. On account of the improved hybrid nanostructure and the synergistic effect between spinel-NiCo2O4 hollow microspheres and RGO nanoflakes, the electrode obtained from Ni wire etched for 10 min, i.e., Ni-10/NCO/RGO exhibits the lowest initial equivalent resistance (1.68 ohm), and displays a good rate capability with a volumetric capacitance (2.64 F/cm(3)) and areal capacitance (25.3 mF/cm(2)). Additionally, the volumetric specific capacitance calculated by considering only active material volume was found to be as high as 253 F/cm(3). It is revealed that the diffusion-controlled process related to faradaic volume processes (battery type) contributed significantly to the surface-controlled process of the Ni-10/NCO/RGO electrode compared to other electrodes that led to the optimum electrochemical performance. Furthermore, the wire-shaped supercapacitor (WSC) was fabricated by assembling two optimum electrodes in-twisted structure with gel electrolyte and the device exhibited 10 mu Wh/cm(3) (54 mWh/kg) energy density and 4.95 mW/cm(3) (27 W/kg) power density at 200 mu A. Finally, the repeatability, flexibility, and scalability of WSCs were successfully demonstrated at various device lengths and bending angles.