Synthesis of cheracterization of cyclopentadienone-Ru complex, and synthesis of SCS catalyst
- 발행기관 서강대학교 대학원
- 지도교수 강재효
- 발행년도 2008
- 학위수여년월 2008. 2
- 학위명 석사
- 학과 및 전공 화학
- 식별자(기타) 000000107726
- 본문언어 영어
목차
Part 1: Synthesis and Chracterization of cyclopentadienone-Ru complex Shvo’s diruthenium complex is an active catalyst in a considerable number of homogeneous reactions. The synthesis and characterization by X-ray crystallography study of a family of Shvo-type cyclopentadienone ruthenium complex derived from (-)-menthone.
Part 2: Synthesis of SCS Pincer catalyst Optically active sulfur containing C2-symmetric SCS pincer ligand was prepared from commercially available starting material.
목차
Part 1: Synthesis and Chracterization of cyclopentadienone-Ru complex (-)-menthone으로부터 유도된 새로운 Shvo-type의 cyclopentadienone-ruthenium complex를 합성하였고 X-ray 단결정 회절법을 이용하여 cyclopentadienone-ruthenium complex의 구조와 dinuclear ruthenabicycle complex의 구조를 알아내었다.
Part 2: Synthesis of SCS Pincer catalyst 황을 포함하고 있는 광학활성을 갖는 팔라듐 및 로듐 촉매인 pincer-type 촉매를 합성을 수행하기 위한 pincer ligand를 합성하였다.
